Light can vaporize water without the need for heat!

It's the most fundamental of processes—the evaporation of water from the surfaces of oceans and lakes, the burning off of fog in the morning sun, and the drying of briny ponds that leaves solid salt behind. Evaporation is all around us, and humans have been observing it and making use of it for as long as we have existed.

And yet, it turns out, we've been missing a major part of the picture all along.

In a series of painstakingly precise experiments, a team of researchers  has demonstrated that heat isn't alone in causing water to evaporate. Light, striking the water's surface where air and water meet, can break water molecules away and float them into the air, causing evaporation in the absence of any source of heat.

The astonishing new discovery could have a wide range of significant implications. It could help explain mysterious measurements over the years of how sunlight affects clouds, and therefore affect calculations of the effects of climate change on cloud cover and precipitation. It could also lead to new ways of designing industrial processes such as solar-powered desalination or drying of materials.

The findings, and the many different lines of evidence that demonstrate the reality of the phenomenon and the details of how it works, are described recently in the Proceedings of the National Academy of Sciences.

The authors say their study suggests that the effect should happen widely in nature—everywhere from clouds to fogs to the surfaces of oceans, soils, and plants—and that it could also lead to new practical applications, including in energy and clean water production.

The new work builds on research reported* last year, which described this new "photomolecular effect" but only under very specialized conditions: on the surface of specially prepared hydrogels soaked with water. In the new study, the researchers demonstrate that the hydrogel is not necessary for the process; it occurs at any water surface exposed to light, whether it's a flat surface like a body of water or a curved surface like a droplet of cloud vapour.

Because the effect was so unexpected, the team worked to prove its existence with as many different lines of evidence as possible. In this study, they report 14 different kinds of tests and measurements they carried out to establish that water was indeed evaporating—that is, molecules of water were being knocked loose from the water's surface and wafted into the air—due to the light alone, not by heat, which was long assumed to be the only mechanism involved.

One key indicator, which showed up consistently in four different kinds of experiments under different conditions, was that as the water began to evaporate from a test container under visible light, the air temperature measured above the water's surface cooled down and then leveled off, showing that thermal energy was not the driving force behind the effect.

Other key indicators that showed up included the way the evaporation effect varied depending on the angle of the light, the exact color of the light, and its polarization. None of these varying characteristics should happen because at these wavelengths, water hardly absorbs light at all—and yet the researchers observed them.

The effect is strongest when light hits the water surface at an angle of 45 degrees. It is also strongest with a certain type of polarization, called transverse magnetic polarization. And it peaks in green light—which, oddly, is the colour for which water is most transparent and thus interacts the least.

Researchers have proposed a physical mechanism that can explain the angle and polarization dependence of the effect, showing that the photons of light can impart a net force on water molecules at the water surface that is sufficient to knock them loose from the body of water. But they cannot yet account for the color dependence, which they say will require further study.

They have named this the photomolecular effect, by analogy with the photoelectric effect that was discovered by Heinrich Hertz in 1887 and finally explained by Albert Einstein in 1905. That effect was one of the first demonstrations that light also has particle characteristics, which had major implications in physics and led to a wide variety of applications, including LEDs. Just as the photoelectric effect liberates electrons from atoms in a material in response to being hit by a photon of light, the photomolecular effect shows that photons can liberate entire molecules from a liquid surface, the researchers say.

The finding of evaporation caused by light instead of heat provides new disruptive knowledge of light-water interaction.
It could help us gain new understanding of how sunlight interacts with cloud, fog, oceans, and other natural water bodies to affect weather and climate. It has significant potential practical applications such as high-performance water desalination driven by solar energy.
The finding may solve an 80-year-old mystery in climate science. Measurements of how clouds absorb sunlight have often shown that they are absorbing more sunlight than conventional physics dictates possible. The additional evaporation caused by this effect could account for the longstanding discrepancy, which has been a subject of dispute since such measurements are difficult to make.

Those experiments are based on satellite data and flight data. They fly an airplane on top of and below the clouds, and there are also data based on the ocean temperature and radiation balance. And they all conclude that there is more absorption by clouds than theory could calculate. However, due to the complexity of clouds and the difficulties of making such measurements, researchers have been debating whether such discrepancies are real or not. And what was discovered now suggests that hey, there's another mechanism for cloud absorption, which was not accounted for, and this mechanism might explain the discrepancies.

There are many lines of evidence. The flat region in the air-side temperature distribution above hot water will be the easiest for people to reproduce. That temperature profile "is a signature" that demonstrates the effect clearly.
It is quite hard to explain how this kind of flat temperature profile comes about without invoking some other mechanism" beyond the accepted theories of thermal evaporation.
The observations in the manuscript points to a new physical mechanism that foundationally alters our thinking on the kinetics of evaporation.

Source: 

Guangxin Lv et al, Photomolecular effect: Visible light interaction with air–water interface, Proceedings of the National Academy of Sciences (2024). DOI: 10.1073/pnas.2320844121

* Yaodong Tu et al, Plausible photomolecular effect leading to water evaporation exceeding the thermal limit, Proceedings of the National Academy of Sciences (2023). DOI: 10.1073/pnas.2312751120